Tetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′,κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)dysprosium(III)]
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چکیده
In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted DyN(2)O(7) monocapped square-anti-prismatic geometry. The title compound is isotypic with its terbium-containing analogue.
منابع مشابه
Tetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′,κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)praseodymium(III)]
In the centrosymmetric binuclear title complex, [Pr(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Pr(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Pr(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted PrN(2)O(7) monocapped ...
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In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phen-oxy-propionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, two O atoms from a chelating carboxyl-ate, two O atoms derived from a μ(3)-carboxylate and two O atoms derived from two μ(2...
متن کاملTetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′;κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)terbium(III)]
In the centrosymmetric binuclear title complex, [Tb(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Tb(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Tb(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted TbN(2)O(7) monocapped ...
متن کاملTetrakis(μ2-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′;κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)lanthanum(III)]
In the centrosymmetric binuclear title complex, [La(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two La(III) ions are linked by four 2-phen-oxy-propionate (L) groups in bi- and tridentate bridging modes. Each La(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate chelating carboxyl-ate group and four bridging carboxyl-ate groups in a distorted LaN(2)O(7) monocapped s...
متن کاملTetrakis(μ2-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′;κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)gadolinium(III)]
In the centrosymmetric binuclear title complex, [Gd(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Gd(III) ions are linked by four 2-phen-oxy-propionate (L) groups in bi- and tridentate bridging modes. Each Gd(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate chelating carboxyl-ate group and four bridging carboxyl-ate groups in a distorted GdN(2)O(7) monocapped s...
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